[1]吴英法,肖嘉鑫,伍洋涛,等.基于酞菁钴强化的便携式高氯酸盐传感器性能[J].中国给水排水,2026,42(1):58-63.
　WUYingfa,XIAOJiaxin,WUYangtao,et al.Performance of a Portable Perchlorate Sensor Enhanced by Cobalt Phthalocyanine[J].China Water & Wastewater,2026,42(1):58-63.
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基于酞菁钴强化的便携式高氯酸盐传感器性能

中国给水排水[ISSN:1000-4062/CN:12-1073/TU] 卷: 第42卷 期数: 2026年第1期 页码: 58-63 栏目: 出版日期: 2026-01-01
Title:
Performance of a Portable Perchlorate Sensor Enhanced by Cobalt Phthalocyanine
作者:
吴英法1,2， 肖嘉鑫1,2， 伍洋涛1,2， 卜令君1,2， 祝淑敏1,2
（1.湖南大学土木工程学院 水安全保障技术及应用湖南省工程研究中心，湖南 长沙410082；2.湖南大学 建筑安全与节能教育部重点实验室，湖南 长沙 410082）
Author(s):
WU　Yingfa1，2， XIAO　Jiaxin1，2， WU　Yangtao1，2， BU　Lingjun1，2， ZHU　Shumin1，2
（1. Hunan Engineering Research Center of Water Security Technology and Application， College of Civil Engineering， Hunan University， Changsha 410082， China； 2. Key Laboratory of Building Safety and Energy Efficiency ， Hunan University， Changsha 410082， China）
关键词:
高氯酸盐;  离子选择电极;  酞菁钴;  便携式传感器
Keywords:
perchlorate;  ion-selective electrode;  cobalt phthalocyanine;  portable sensor
摘要:
以二氯磷四苯基卟啉氯化物（PCl2TPP）作为离子选择载体，通过添加酞菁钴（CoPc）和碳纳米管（CNT），成功制备了复合材料CoPc@ISM/CNT。该复合材料对高氯酸盐表现出较高的灵敏度和选择性，检测线性范围为4.5×10-7~0.1 mol/L，检测限为0.3 μmol/L。CoPc的添加增强了对高氯酸盐的检出效果，CNT则极大提高了电流响应。通过进一步设计复合电极、结合定量分析软件，研发了一种便携式高氯酸盐传感器。对实际水样进行测试，该传感器的回收率在98.5%~106.9%之间，可实现对水中高氯酸盐的实地监测。
Abstract:
This study successfully synthesized a composite material, CoPc@ISM/CNT, using dichlorophosphorus tetraphenylporphyrin chloride (PCl2TPP) as an ion-selective carrier, with the addition of cobalt phthalocyanine (CoPc) and carbon nanotubes (CNT). This composite material exhibited high sensitivity and selectivity toward perchlorate, with a linear detection range of 4.5×10-7 mol/L to 0.1 mol/L and a detection limit of 0.3 μmol/L. The addition of CoPc enhanced the detection of perchlorate, while CNT significantly improved the current response. By further designing a composite electrode and integrating it with quantitative analysis software, a portable perchlorate sensor was developed. Tests on real water samples demonstrated that the sensor achieved recovery rates between 98.5% and 106.9%, enabling on-site monitoring of perchlorate in water.

相似文献/References:

[1]刘珏,杨啸,曹振,等.季铵改性粉末活性炭强化高氯酸盐去除效能与机理[J].中国给水排水,2025,41(17):69.
　LIUJue,YANGXiao,CAOZhen,et al.Quaternary Ammonium?modified Hydrophobic Powdered Activated Carbon for Enhanced Perchlorate Removal and Its Mechanism[J].China Water & Wastewater,2025,41(1):69.

更新日期/Last Update: 2026-01-01