WU Qing,JIA Yan,CUI Yan-rui,et al.Effects of BAC on N2O Production during Biological Nitrogen Removal Process in SBR under Different C/N Ratios[J].China Water & Wastewater,2021,37(9):33-39.
生物活性炭对SBR生物脱氮过程中N2O产生的影响
- Title:
- Effects of BAC on N2O Production during Biological Nitrogen Removal Process in SBR under Different C/N Ratios
- 关键词:
- 生物活性炭; 序批式活性污泥反应器; 同步硝化反硝化; N2O; C/N值
- Keywords:
- biological activated carbon(BAC); sequencing batch reactor(SBR); simultaneous nitrification and denitrification (SND); N2O; C/N ratio
- 摘要:
- 为考察生物活性炭(BAC)对不同C/N值废水脱氮过程中N2O产生的影响,在序批式活性污泥反应器(SBR)中加入活性炭形成SBRBAC,并与活性污泥SBR(SBRAS)进行了比较。以甲醇为碳源配制人工废水,控制进水C/N值分别为3、6和9,在室温(15~27 ℃)条件下同步运行两个反应器,并测定N2O、NH4+-N、NO3--N、NO2--N和TN浓度变化,分析BAC影响N2O产生的机制。在控制混合液DO为2.0~3.0 mg/L条件下,C/N值为3时BAC对N2O的产生没有影响,C/N值为6时BAC可以减少N2O产生,C/N值为9时BAC导致N2O浓度增加;BAC的存在促进了同步硝化反硝化(SND)的进行,进而影响N2O的产生;C/N值是影响脱氮效果和N2O产生的重要因素,COD下降拐点处复杂的反应环境为SND提供了必要条件,BAC能够强化该拐点处的反应条件。
- Abstract:
- In order to investigate the effects of biological activated carbon (BAC) on N2O production in biological nitrogen removal process for different C/N ratio wastewater,activated carbon was added to sequencing batch reactor (SBR) to form BAC-SBR (SBRBAC), and compared with activated sludge SBR (SBRAS). At room temperature of 15-27 ℃, methanol was used as the carbon source to prepare artificial wastewater, the influent C/N ratio was adjusted to be 3, 6 and 9 respectively, and the two reactors were operated simultaneously. The concentrations of N2O,NH4+-N,NO3--N,NO2--N and TN were measured. And also the mechanism of BAC affecting N2O production was analyzed. The experimental results showed that when DO in mixed liquid was controlled at 2.0-3.0 mg/L, and C/N ratio was 3, BAC had no effect on N2O production; when the C/N ratio was 6, BAC could reduce N2O production; and when the C/N ratio was 9, BAC led to an increase in N2O concentration. The presence of BAC promoted simultaneous nitrification and denitrification (SND), which affected the production of N2O; C/N ratio of wastewater was an important factor that affected the effect of denitrification and N2O. The complex reaction environment at the inflection point of COD decline provided the necessary conditions for SND, and BAC could strengthen the reaction conditions at this inflection point.
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