LIUChong,XUWei-yi,LIYu-guang,et al.Deep Denitrification of Cremation Flue Gas Absorption Wastewater Based on Sulfur Autotrophic Denitrification[J].China Water & Wastewater,2022,38(11):7-12.
火化烟气吸收液的硫自养反硝化深度脱氮研究
- Title:
- Deep Denitrification of Cremation Flue Gas Absorption Wastewater Based on Sulfur Autotrophic Denitrification
- Keywords:
- cremation flue gas; deep denitrification; autotrophic denitrification; sulfate; microbial community structure
- 摘要:
- 基于硫自养反硝化工艺研究了火化烟气吸收液的深度脱氮过程与调控技术。通过逐级提高硝态氮负荷的方式可以在30 d内使硝态氮去除率提高至89.0%,石灰石可以有效替代碳酸氢钠为反应系统提供碱度,使自养反硝化菌群稳定发挥脱氮能力。相比于硫酸盐,亚硝态氮表现出更为明显的自养反硝化功能菌群毒性抑制效果,但是在功能菌群适应进水水质后,系统的硝态氮去除率均高于93.2%。定期反冲洗可以防止硫磺填料板结现象的发生,从而使系统维持较好的硝态氮去除效果。Thiobacillus sp.和Sulfrimonas sp.是系统中的优势菌群,相对丰度占总自养脱氮功能菌群的70.5%以上,但是Sulfuricurvum sp.的相对丰度则明显降低,主要原因在于其不能还原亚硝态氮。
- Abstract:
- Based on the sulfur autotrophic denitrification process, the deep denitrification process and control technology of cremation flue gas absorption wastewater were studied. It was found that nitrate removal could be increased to 89.0% within 30 days by gradually increasing the nitrate loading. Limestone could effectively substitute NaHCO3 to provide alkalinity, and thus the autotrophic denitrifying bacteria could perform stable nitrogen removal capacity. Compared with sulfate, nitrite showed obvious toxic inhibition effect on the autotrophic denitrifying bacteria. However, the removal efficiency of nitrate was higher than 93.2% when the functional flora adapted to the influent quality. Regular backwashing could prevent the occurrence of sulfur packing hardening, therefore, the system could maintain good nitrate removal performance. Thiobacillus sp. and Sulfrimonas sp. were the dominant species, and the relative abundance accounted for more than 70.5%, but the relative abundance of Sulfuricurvum sp. was significantly lower, mainly because Sulfuricurvum sp. could not reduce the nitrite.
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