[1]鄢胜韩,黄恒旭,卓桂华,等.不同比例葡萄糖和蛋白质对微生物电解池产氢影响[J].中国给水排水,2023,39(13):95-102.
　YANSheng-han,HUANGHeng-xu,ZHUOGui-hua,et al.Effect of Different Mixing Ratio of Glucose and Protein in Substrate on Hydrogen Production in Microbial Electrolytic Cell[J].China Water & Wastewater,2023,39(13):95-102.
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不同比例葡萄糖和蛋白质对微生物电解池产氢影响

中国给水排水[ISSN:1000-4062/CN:12-1073/TU] 卷: 第39卷 期数: 2023年第13期 页码: 95-102 栏目: 出版日期: 2023-07-01
Title:
Effect of Different Mixing Ratio of Glucose and Protein in Substrate on Hydrogen Production in Microbial Electrolytic Cell
作者:
鄢胜韩1,2， 黄恒旭1， 卓桂华3， 曾艺芳4， 江娟5， 刘常青6， 甄广印7， 郑育毅1,2
（1.福建师范大学环境与资源学院、碳中和现代产业学院 福建省污染控制与资源循环利用重点实验室，福建 福州 350007；2.城市废物资源化技术与管理福建省高校工程研究中心，福建 福州 350007；3.福建省环境科学研究院，福建 福州 350013；4.福建省闽环试验检测有限公司，福建 福州 350012；5.福建省厦门环境监测中心站，福建 厦门 361022；6.福建师范大学 地理科学学院、碳中和未来技术学院，福建 福州 350007；7.华东师范大学 生态与环境科学学院，上海 200241）
Author(s):
YAN　Sheng-han1，2， HUANG　Heng-xu1， ZHUO　Gui-hua3， ZENG　Yi-fang4， JIANG　Juan5， LIU　Chang-qing6， ZHEN　Guang-yin7， ZHENG　Yu-yi1，2
（1. Fujian Key Laboratory of Pollution Control and Resource Reuse，College of Environmental and Resource Sciences and College of Carbon Neutral Modern Industry，Fujian Normal University，Fuzhou 350007， China； 2. Fujian College and University Engineering Research Center for Municipal Waste Resourcization and Management， Fuzhou 350007， China； 3. Fujian Academy of Environmental Sciences，Fuzhou 350013， China； 4. Fujian Minhuan Test and Detection Co. Ltd.， Fuzhou 350012， China； 5. Xiamen City Environmental Monitoring Center Station， Xiamen 361022， China； 6. School of Geographical Sciences and School of Carbon Neutrality Future Technology， Fujian Normal University， Fuzhou 350007， China； 7. School of Ecological and Environmental Science， East China Normal University， Shanghai 200241， China）
关键词:
微生物电解池（MEC）;  产氢;  葡萄糖;  蛋白质
Keywords:
microbial electrolytic cell (MEC);  hydrogen production;  glucose;  protein
摘要:
微生物电解池（MEC）能有效降解污泥有机质并获取清洁能源，其产氢效能受底物性质的影响显著。通过以葡萄糖与牛血清白蛋白（BSA）为碳水化合物与蛋白质的模拟底物开展MEC批式循环试验，探究不同比例（1∶0、5∶1、1∶1、1∶5、0∶1，以COD计）的葡萄糖和BSA基质在MEC中的产氢性能。结果表明：葡萄糖较BSA更易被产电菌利用，产氢性能更优，在葡萄糖和BSA比例为1∶0的试验组中产氢量最高可达（28.96±3.45） mL；随着BSA的增加，氢气产率明显降低，葡萄糖的去除率也有所降低，从（98.65±0.70）%下降至（92.24±1.84）%。在以BSA为主的试验组（葡萄糖和BSA比例为1∶5、0∶1）中发现所产氢气更快速地转化为CH4，同时葡萄糖影响了BSA的降解效率，其降解率为（38.49±4.31）%~（44.96±5.13）%；葡萄糖也影响了BSA的转化途径，具体表现为蛋白质降解副产物NH4+-N的产量降低。
Abstract:
Hydrogen production from microbial electrolysis cell (MEC) can effectively degrade sludge organic matters to obtain clean energy, and its hydrogen production efficiency is significantly affected by substrate properties. A batch cycle experiment was carried out to investigate the effect of mixing ratio (1∶0, 5∶1, 1∶1, 1∶5 and 0∶1, calculated by COD) of glucose to bovine serum albumin (BSA) on hydrogen production in MEC. The simulated substrate consisted of glucose (carbohydrate) and BSA (protein). Glucose in MEC was more easily utilized than BSA, and had better hydrogen production performance. In the experimental group with glucose to BSA ratio of 1∶0, the hydrogen production reached (28.96±3.45) mL. With the increase of BSA, the hydrogen yield decreased significantly, and the glucose removal rate decreased from (98.65±0.70)% to (92.24±1.84)%. In the experimental groups dominated by BSA (the ratios of glucose to BSA were 1∶5 and 0∶1), hydrogen was more rapidly converted to CH4. In addition, glucose affected the degradation efficiency of BSA, and the degradation rate ranged from (38.49±4.31)% to (44.96±5.13)%. Glucose also affected the conversion pathway of BSA, which could be proved by the decreasing production of ammonia nitrogen (a by-product of protein degradation).
更新日期/Last Update: 2023-07-01