LAN Mei,YING Yuan-yuan,LUO Hai-hui,et al.Sludge Conditioning Mechanism of Typical Wastewater Treatment Processes[J].China Water & Wastewater,2023,39(15):94-100.
典型污水处理工艺的污泥调理机制研究
- Title:
- Sludge Conditioning Mechanism of Typical Wastewater Treatment Processes
- Keywords:
- sludge dewatering; persulfate; fluorescent protein; EEM
- 摘要:
- 为分析经过硫酸盐高级氧化处理后的市政污泥荧光蛋白组成和含量的变化及其对提高污泥脱水性能的影响,用二价铁活化过硫酸氢钾(PMS)调理三种不同工艺产生的市政污泥,并采用三维荧光光谱(EEM)和平行因子分析法(PARAFAC)进行分析。结果表明,类色氨酸蛋白是影响污泥脱水性能的重要因素,降低类色氨酸蛋白含量可以有效提高污泥脱水性能。从结构上看,在市政污泥胞外聚合物(EPS)中,类色氨酸蛋白的含量从内层紧密黏附型胞外聚合物(TB-EPS)向外层可溶性胞外聚合物(S-EPS)逐渐减少,其中TB-EPS是决定污泥脱水性能的微生物保护层。而以氧化沟为代表的污水处理工艺产生的剩余污泥比AAO和MSBR产生的剩余污泥更难脱水,这缘自于氧化沟工艺微生物处于内源呼吸期所形成的芽孢或其他休眠体保护,因此对于氧化沟污泥的调理脱水需要通过其他更有针对性的技术实现。
- Abstract:
- This paper conditioned the municipal sludge produced by three different processes by divalent iron activated peroxynitrite (PMS), and analyzed the changes in fluorescent protein composition and content of municipal sludge after peroxynitrite advanced oxidation treatment and its effect on improving sludge dewatering performance by three-dimensional fluorescence spectroscopy (EEM) and parallel factor analysis (PARAFAC). Tryptophan-like protein was an important factor affecting the sludge dewatering performance, and reducing tryptophan-like protein content effectively improved the sludge dewatering performance. From the perspective of structure, the content of tryptophan?like protein in extracellular polymeric substance (EPS) of municipal sludge gradually decreased from the inner layer of tightly bounded EPS (TB?EPS) to the outer layer of soluble EPS (S-EPS), in which TB-EPS was the microbial protective layer that determined the sludge dewatering performance. However, the excess sludge from wastewater treatment processes represented by oxidation ditch was more difficult to dewater than the excess sludge from AAO and MSBR, which was due to the protection of spores or other dormant bodies formed by microorganisms in the oxidation ditch process during the endogenous respiratory period. Therefore, the conditioning and dewatering of sludge from oxidation ditch needs to be realized by other more targeted conditioning technologies.
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