XIAOFeng,ZHENGDe-duo,WEIYue-hua,et al.Identification and Spatial Distribution Analysis of Membrane Fouling in Ultrafiltration Systems in a Drinking Water Treatment Plant[J].China Water & Wastewater,2025,41(15):47-54.
某水厂超滤膜污染物识别及空间分布特征解析
- Title:
- Identification and Spatial Distribution Analysis of Membrane Fouling in Ultrafiltration Systems in a Drinking Water Treatment Plant
- 摘要:
- 超滤膜污染行为与机制已得到广泛研究,但现有成果多聚焦于污染物时序变化规律及整体污染特性分析,对膜表面污染物的空间分布特征研究明显不足。为此,立足于水厂实际运行的超滤膜组件,通过对不同空间点位的膜污染物进行萃取,结合SEM、FTIR、XPS和EDS等原位表征技术,解析了超滤膜污染在膜组件三维空间的分布特征。结果表明,超滤膜污染主要是源于腐殖酸、多糖等有机物与Fe、Mn、Al等无机物形成的复合污染;污染物在膜组件纵向上呈现“进水断面>中间断面>出水断面”的分布规律,横向上呈现 “内层>中层>外层”的分布规律。基于此可优化超滤膜的清洗策略,并优化膜组件设计。
- Abstract:
- At present, the fouling behavior and mechanism of ultrafiltration(UF) membranes have been widely studied, but the existing achievements mostly focus on the temporal variation patterns of foulants and overall fouling characteristics, and the exploration of the spatial distribution features of foulants on membrane surfaces is obviously insufficient. This study investigated UF membrane modules operating in actual water treatment plants. By extracting and analyzing foulants from distinct spatial locations and employing in-situ characterization techniques such as SEM, FTIR, XPS, and EDS, the three-dimensional spatial distribution characteristics of UF membrane fouling within modules were comprehensively elucidated. Results indicated that UF membrane fouling primarily arose from composite contaminants formed by organic substances (e.g., humic acids, polysaccharides) and inorganic components (e.g., Fe, Mn, Al). The foulants exhibited distinct spatial distribution patterns: a longitudinal gradient of “inlet section>middle section>outlet section” and a transverse progression of “inner layer> middle layer>outer layer”. These findings offer technical insights for optimizing membrane cleaning strategies and establish a theoretical foundation for advanced membrane module design.
相似文献/References:
[1]杨斐,刘宏远,朱海涛,等.强化组合超滤技术处理污染水源水[J].中国给水排水,2020,36(7):42.
[2]王慧文,陈卫,陶辉.预氧化/超滤组合除锰工艺的膜污染特性[J].中国给水排水,2020,36(9):22.
[3]王小兵,游浩荣,叶元柳,等.PAC/UF工艺处理微污染水源水的膜污染特性[J].中国给水排水,2020,36(11):27.
[4]高倩,张崇淼,魏样,等.饮用水超滤处理中的膜污染及减缓技术研究进展[J].中国给水排水,2020,36(18):13.
GAO Qian,ZHANG Chong-miao,WEI Yang,et al.Research Progress of Membrane Fouling and Mitigation Techniques in Ultrafiltration Treatment of Drinking Water[J].China Water & Wastewater,2020,36(15):13.
[5]刘建林,谢杰.膜芬顿技术在污水深度处理中的应用[J].中国给水排水,2020,36(22):145.
LIU Jian-lin,XIE Jie.Application of Membrane Fenton Coupling Technology in Wastewater Advanced Treatment[J].China Water & Wastewater,2020,36(15):145.
[6]苏菲,李英华,李海波,等.电絮凝/氧化—超滤协同去除水中NOM的研究[J].中国给水排水,2020,36(23):31.
SU Fei,LI Ying-hua,LI Hai-bo,et al.Removal of Natural Organic Matter by Electro-coagulation/Oxidation-Ultrafiltration Technology[J].China Water & Wastewater,2020,36(15):31.
[7]王金龙.再生水厂UF-RO双膜工艺的设计探讨及优化改进[J].中国给水排水,2020,36(24):120.
WANG Jin-long.Discussion and Improvement on Design of UF and RO Process in a Water Reclamation Plant[J].China Water & Wastewater,2020,36(15):120.
[8]何林娟,邹康兵,盛云鸽,等.预处理对东江原水超滤过程中膜污染的控制作用[J].中国给水排水,2021,37(1):16.
HE Lin-juan,ZOU Kang-bing,SHENG Yun-ge,et al.Control Effect of Pretreatment on Membrane Fouling during Ultrafiltration of Dongjiang River Raw Water[J].China Water & Wastewater,2021,37(15):16.
[9]于海宽,李星,周志伟,等.大型超滤水厂PVC和PVDF膜运行特性差异与优化[J].中国给水排水,2021,37(1):28.
YU Hai-kuan,LI Xing,ZHOU Zhi-wei,et al.Operation Characteristics and Optimization of PVC and PVDF Membranes in Full-scale Ultrafiltration Drinking Water Treatment Plant[J].China Water & Wastewater,2021,37(15):28.
[10]郑利祥,郭中权,毛维东.矿井水处理聚合氯化铝残留物对超滤膜污染的影响[J].中国给水排水,2021,37(1):51.
ZHENG Li-xiang,GUO Zhong-quan,MAO Wei-dong.Influence of Polyaluminium Chloride Residue on Ultrafiltration Membrane Fouling in Mine Water Treatment[J].China Water & Wastewater,2021,37(15):51.