[1]左亮,冯晓楠,黄胜超,等.黄磷生产废水中磷形态解析及分布特征[J].中国给水排水,2026,42(5):105-111.
　ZUOLiang,FENGXiaonan,HUANGShengchao,et al.Analysis and Distribution Characteristics of Phosphorus Forms in Yellow Phosphorus Production Wastewater[J].China Water & Wastewater,2026,42(5):105-111.
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黄磷生产废水中磷形态解析及分布特征

中国给水排水[ISSN:1000-4062/CN:12-1073/TU] 卷: 第42卷 期数: 2026年第5期 页码: 105-111 栏目: 出版日期: 2026-03-01
Title:
Analysis and Distribution Characteristics of Phosphorus Forms in Yellow Phosphorus Production Wastewater
作者:
左亮1， 冯晓楠1， 黄胜超2， 许金宝1， 宋珮瑶1， 廖良栋2， 卢仕玉2， 刘颖1， 罗凡1
（1.华中科技大学 环境科学与工程学院，湖北 武汉 430074；2.湖北兴发化工集团股份有限公司，湖北 宜昌 443711）
Author(s):
ZUO　Liang1， FENG　Xiaonan1， HUANG　Shengchao2， XU　Jinbao1， SONG　Peiyao1， LIAO　Liangdong2， LU　Shiyu2， LIU　Ying1， LUO　Fan1
（1. School of Environmental Science and Engineering， Huazhong University of Science and Technology， Wuhan 430074， China； 2. Hubei Xingfa Chemicals Group Co. Ltd.， Yichang 443711， China）
关键词:
黄磷生产废水;  磷检测;  磷形态;  磷回收;  密度泛函理论
Keywords:
yellow phosphorus production wastewater;  phosphorus detection;  phosphorus form;  phosphorus recovery;  density functional theory
摘要:
新兴行业的快速发展使得磷资源变得紧缺，同时黄磷生产急需绿色资源化改造，因此考虑对其高浓度磷酸盐生产废水进行磷资源回收。然而目前对黄磷生产废水中的复杂磷形态缺乏系统性的检测手段，资源化回收工作难以开展。为此，以湖北某黄磷企业生产废水为例，归纳提出不同磷形态的定性解析和定量检测方法，考察典型黄磷生产工艺不同节点的废水磷形态分布情况，提出不同磷形态转化途径，并基于密度泛函理论计算分析转化机理。结果表明，该解析和检测方法适用于复杂磷形态水样，黄磷生产废水中的磷含量最高可达40 g/L，大多数水样在17 g/L左右，其中约70%为正磷酸盐，具有较高的磷资源回收利用价值，可为黄磷化工行业的资源化提供参考。
Abstract:
The rapid development of emerging industries has led to a shortage of phosphorus resources, while the yellow phosphorus production industry urgently requires green and resource-efficient transformation. Therefore, the recovery of phosphorus resources from high-concentration phosphate production wastewater is being considered. However, the lack of systematic detection methods for complex phosphorus forms in yellow phosphorus production wastewater has hindered resource recovery efforts. Taking the production wastewater from a yellow phosphorus enterprise in Hubei as an example, this study summarized qualitative analysis and quantitative detection methods for different phosphorus forms, investigated the distribution characteristics of phosphorus forms in wastewater from different nodes of a typical yellow phosphorus production process, proposed transformation pathways for different phosphorus forms, and analyzed the transformation mechanisms based on density functional theory calculations. The results showed that the proposed analytical and detection methods were applicable to water samples with complex phosphorus forms. The phosphorus content in yellow phosphorus production wastewater could reach up to 40 g/L, with most samples around 17 g/L, of which approximately 70% was orthophosphate, indicating high potential for phosphorus resource recovery and utilization. This study provides a reference for resource utilization in the yellow phosphorus chemical industry.
更新日期/Last Update: 2026-03-01