WangJian,HuangJing,Wan Peng,et al.Operational Performance and Antifouling Mechanisms of a Conductive Ultrafiltration Membrane under Electrical Enhancement[J].China Water & Wastewater,2026,42(15):1-8.
电赋能复合导电超滤膜的运行特性与抗污染机理
- Title:
- Operational Performance and Antifouling Mechanisms of a Conductive Ultrafiltration Membrane under Electrical Enhancement
- 关键词:
- 膜生物反应器(MBR); 膜污染; 跨膜压差; 导电超滤膜; 电赋能
- Keywords:
- membrane bioreactor (MBR); membrane fouling; transmembrane pressure; conductive ultrafiltration membrane; electrical assistance
- 摘要:
- 为缓解膜生物反应器(MBR)长期运行过程中的膜污染问题,构建了一种电赋能复合导电超滤膜(E-UF),并在实际市政污水条件下开展与普通超滤膜(UF)的长期对比实验,系统分析其运行特性及抗污染机理。结果表明,在实现COD、TN及NH4+-N去除效果稳定的前提下,E-UF的跨膜压差(TMP)显著降低,稳定期的TMP较UF降低83.6%~90.6%,抽吸比能耗同步下降;三维荧光光谱分析显示,E-UF出水中蛋白类有机物及微生物代谢产物的荧光强度明显减弱;微生物群落分析表明,E-UF中反硝化相关菌属富集、潜在电子竞争菌减少;KEGG功能预测显示反硝化关键功能基因丰度提高,氮循环网络向更完整的反硝化路径偏移。电赋能运行通过电子分配优化与氮循环功能重构,削减污染前驱物生成并抑制滤饼层压实,实现对膜污染发展的有效控制,为电化学与生物处理耦合调控膜污染提供了理论依据。
- Abstract:
- To mitigate membrane fouling in the membrane bioreactors (MBR), an electrically assisted conductive ultrafiltration membrane unit (E-UF) was developed and operated in parallel with a conventional ultrafiltration (UF) membrane under real municipal wastewater conditions. The operational performance and antifouling mechanisms were systematically investigated. The results showed that, while maintaining stable COD, TN and NH4+-N removal efficiencies, the E-UF system significantly suppressed transmembrane pressure (TMP) development, with steady-state TMP reduced by 83.6%-90.6% compared to the UF. The corresponding specific suction energy consumption was also markedly decreased. Excitation-emission matrix (EEM) analysis showed that the fluorescence regions associated with protein-like organic matter and microbial metabolic products in the E-UF effluent were markedly reduced. Microbial community analysis indicated enrichment of denitrification-related genera and reduction of potential electron-competing bacteria in E-UF. KEGG-based functional prediction further demonstrated enhanced abundances of key denitrification genes, suggesting a functional shift toward a more complete denitrification pathway. Electrically assisted operation optimized electron allocation and reshaped nitrogen metabolic networks, thereby reducing fouling precursor production and mitigating cake layer compaction. This study provides mechanistic insights into the coupling of electrochemical regulation and biological nitrogen transformation for sustainable fouling control in MBR systems.
相似文献/References:
[1]郝晓地,陈峤,李季,等.MBR工艺全球应用现状及趋势分析[J].中国给水排水,2018,34(20):7.
HAO Xiao di,CHEN Qiao,LI Ji,et al.Status and Trend of MBR Process Application in the World[J].China Water & Wastewater,2018,34(15):7.
[2]常新强,林涛,陈卫,等.PAC/PS预处理对水中镉的去除及UF膜污染控制[J].中国给水排水,2022,38(1):64.
CHANG Xin-qiang,LIN Tao,CHEN Wei,et al.PAC/PS Pretreatment Process for Removal of Cadmium from Water and Control of Ultrafiltration Membrane Fouling[J].China Water & Wastewater,2022,38(15):64.
[3]王志红,植许鋆,李炳萱,等.KMnO4强化混凝耦合超滤去除湖库水中共存铁锰藻[J].中国给水排水,2022,38(5):1.
WANGZhi-hong,ZHIXu-jun,LIBing-xuan,et al.Potassium Permanganate Pre-oxidation Enhanced Coagulation Coupled with Ultrafiltration to Remove Co-existed Iron, Manganese and Algae in Lakes and Reservoirs in South China[J].China Water & Wastewater,2022,38(15):1.
[4]侯琮语,李佳宾,付宛宜,等.臭氧/陶瓷膜-活性炭组合工艺处理农村饮用水中试[J].中国给水排水,2022,38(8):38.
HOUCong-yu,LIJia-bin,FUWan-yi,et al.A Combined Ozone/Ceramic Membrane and Activated Carbon Process for Rural Drinking Water Treatment: A Pilot Study[J].China Water & Wastewater,2022,38(15):38.
[5]李志超,肖宁,林蔓,等.MBBR耦合MBR用于东北某低温高排放标准污水厂[J].中国给水排水,2022,38(14):77.
LIZhi-chao,XIAONing,LINMan,et al.Application of MBBR Coupled with MBR Process in a Stringent Discharge Standard Wastewater Treatment Plant in Northeast China at Low Temperature[J].China Water & Wastewater,2022,38(15):77.
[6]毛鑫,张冰,唐和礼,等.生物法减缓MBR膜污染的研究进展[J].中国给水排水,2022,38(18):34.
MAOXin,ZHANGBing,TANGHe-li,et al.Research Progress of Biological Methods to Mitigate MBR Membrane Fouling[J].China Water & Wastewater,2022,38(15):34.
[7]王凤雪,张新波,尚禹彤,等.MBBR—MBR对磺胺嘧啶的去除及膜污染特性[J].中国给水排水,2023,39(1):80.
WANGFeng-xue,ZHANGXin-bo,SHANGYu-tong,et al.MBBR-MBR System for Removal of Sulfadiazine and Its Membrane Fouling Characteristics[J].China Water & Wastewater,2023,39(15):80.
[8]韦纯忠,曾思,李冬冬,等.GO-PVP/PVDF渗透膜的热质传递机理和污染特性[J].中国给水排水,2023,39(5):80.
WEI Chun-zhong,ZENG Si,LI Dong-dong,et al.Heat and Mass Transfer Mechanism and Membrane Fouling Characteristics of GO-PVP/PVDF Permeable Membrane[J].China Water & Wastewater,2023,39(15):80.
[9]廖德祥,琚佳琪,魏福强,等.电去离子法提取垃圾渗滤液中氨氮的研究[J].中国给水排水,2023,39(5):106.
LIAODe-xiang,JUJia-qi,WEIFu-qiang,et al.Electrodeionization Method for Recovery of Ammonia Nitrogen from Landfill Leachate[J].China Water & Wastewater,2023,39(15):106.
[10]余健鑫,钟绮芸,龙志宏,等.基于XDLVO理论的亲疏水组分对超滤膜污染的影响[J].中国给水排水,2023,39(7):35.
YUJian-xin,ZHONGQi-yun,LONGZhi-hong,et al.Effect of Hydrophobic/Hydrophilic Components on Ultrafiltration Membrane Fouling Based on XDLVO Theory[J].China Water & Wastewater,2023,39(15):35.