WANGFeng-xue,ZHANGXin-bo,SHANGYu-tong,et al.MBBR-MBR System for Removal of Sulfadiazine and Its Membrane Fouling Characteristics[J].China Water & Wastewater,2023,39(1):80-85.
MBBR—MBR对磺胺嘧啶的去除及膜污染特性
- Title:
- MBBR-MBR System for Removal of Sulfadiazine and Its Membrane Fouling Characteristics
- Keywords:
- MBBR; MBR; sulfadiazine; antibiotics; membrane fouling
- 摘要:
- 构建MBBR—MBR耦合系统,在低碳氮比(C/N=2.5)污水条件下,探究该系统对磺胺嘧啶(SDZ)的去除效能,同时分析SDZ对常规污染物去除效果及膜污染的影响。结果表明,MBBR—MBR耦合系统对SDZ(0.5 mg/L)的去除率最高可达到61.9%,其中,MBBR与MBR单元对SDZ的平均去除率分别为42.3%和15.4%。SDZ的存在使氨氮、总氮、总有机碳的去除率以及同步硝化反硝化率分别降低了11.81%、8.41%、5.77%、3.40%,同时使得污泥平均粒径减小了3~4 μm,且MBR单元中溶解性微生物产物(SMP)的多糖浓度增加了0.35 mg/gMLVSS,MBR中跨膜压差(TMP)的增长速率增加了0.36 kPa/d,可见SDZ导致膜污染速率上升。
- Abstract:
- A coupled MBBR-MBR system was constructed to explore its enhanced performance for removing sulfadiazine (SDZ) from wastewater with low ratio of carbon to nitrogen (C/N=2.5), and to evaluate the effect of SDZ on conventional pollutants removal and membrane fouling. The removal rate of SDZ (0.5 mg/L) by the MBBR-MBR coupling system was up to 61.9%, and the average removal rates of SDZ by MBBR and MBR were 42.3% and 15.4%, respectively. The presence of SDZ reduced the removal rate of ammonia nitrogen, total nitrogen and total organic carbon and the simultaneous nitrification and denitrification rate by 11.81%, 8.41%, 5.77% and 3.40%, respectively. In addition, the average particle size of sludge was reduced by 3-4 μm, the polysaccharide concentration of soluble microbial products (SMP) in MBR was increased by 0.35 mg/gMLVSS, and the growth rate of transmembrane pressure in MBR was increased by 0.36 kPa/d, indicating that SDZ led to the increase of membrane fouling rate.
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